after some team mate or colleagues left the team, we might just keep their contacts in our skype contact list. eventually the contact will be displayed as unavailable, when we try to remove them from the list. we click on the confirmation button, but the contact never have been able to removed from list.
the quick solution is very easy and quick.
First we need to completely exit from Skype applicatio.
Second launch the outlook portal in light mode
https://outlook.office365.com/owa/?exsvurl=1&layout=light
Third click on the Contact Folder on the left navigation panel
Four. Type in contact name in the filter textbox, then select it and delete, then re-launch your Skype for business, we will see those contacts should be all gone.